Electrocatalytic and Conductive Vanadium Oxide on Carbonized Bacterial Cellulose Aerogel for the Sulfur Cathode in Li-S Batteries

Many transition-metal-oxide-based catalysts have been investigated to chemically bind soluble lithium polysulfides and accelerate their redox kinetics in lithium-sulfur (Li-S) battery chemistry. However, the intrinsic poor electrical conductivities of these oxides restrict catalytic performance, consequently limiting sulfur utilization rate performance Li-S batteries. Herein, we report a freestanding electrocatalytic host consisting hydrogen-treated VO2 nanoparticles (H-VO2) anchored on nitrogen-doped carbonized bacterial cellulose aerogels (N-CBC). The hydrogen treatment enables formation stabilization rutile VO2(R) phase with metallic conductivity at room temperature, significantly enhancing its capability compared as-synthesized insulative VO2(M) phase. Several measurements characterize this unique H-VO2@N-CBC structure. In particular, two kinetic barriers between S8, polysulfides, Li2S are largely reduced by 28.2 43.3 kJ/mol, respectively. Accordingly, terms charge/discharge rate, is greatly improved. This work suggests an effective strategy develop conductive based typical transition metal oxide (VO2) for